I am getting a lot of conflicting info regarding these finishes. It was my understanding that the greenish park was Zinc Phosphate.
Uncle Bob - Thank you for this info. Is there any more info you might be able to provide about the older finishes which are now not possible to get due to OSHA regulations?
Sorry I had to go back and dig up my notes on this since it's been to long:
Early WW2 was iron phosphate with zinc chromate dip until mid 1943 “the green stuff” Federal Specification TT-C-490 Type II.
Zinc Phosphate: is used on both raw ferrous and galvanized substrates. This material is considered hazardous and must be processed through a wastewater treatment system before dumping to drain. Depending upon the coating weight of the zinc phosphate, this pretreatment can provide 750 hours of corrosion protection over raw steel and up to 1,000 hours of corrosion protection over galvanized steel. It also provides excellent adhesion for powder coating.
Late WW2 and Korea Zinc phosphate and postwar reworks “the gray stuff” - Bonderiite is the common trade name, dates from WW2 Germany by Henkel Aircraft, still sold under that name.
Iron Phosphate: is the most popular pretreatment used on ferrous products. It provides both corrosion resistance and better adhesion for powder coating than the raw substrate. It is considered non-hazardous, and can be dumped to drain in most parts of the country after the oils are removed. Depending upon the number of stages in the pretreatment system and if a sealer (such as Zinc chromate) is used, this pretreatment can provide between 250 hours and 500 hours of salt spray corrosion protection over steel. It also provides excellent adhesion for the powder coating.
Manangese phosphate, Vietnam era and later manganese phosphate, “the black stuff” – FN process is called ”Fermangan”, same as MIL-DTL-16232 Type M
I can post links for this if you want.